[μ-Bis(diphenylarsanyl)methane-1:2κ2 As:As’]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)
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چکیده
In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)], the bis-(diphenyl-arsanyl)methane ligand bridges an Ru-Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. Both arsine and phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 57.91 (19), 84.31 (15) and 59.37 (18)° with each other. The dihedral angles between the two benzene rings are 60.9 (2) and 85.40 (18)° for the two diphenyl-arsanyl groups. In the crystal, mol-ecules are linked into a three-dimensional framework by inter-molecular C-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯π inter-actions stabilize the crystal structure.
منابع مشابه
[μ-Bis(diphenylarsino)methane-1:2κ2 As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-triangulo-triruthenium(0) dichloromethane 0.15-solvate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(20)H(19)O(2)P)(CO)(9)]·0.15CH(2)Cl(2), contains one mol-ecule of the triangulo-triruthenium complex and one partially occupied dichloro-methane solvent mol-ecule. The dichloro-methane solvent lies across a crystallographic inversion center leading to the mol-ecule being disordered over two positions of e...
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The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(18)H(14)BrP)(CO)(9)]·0.3CHCl(3), contains one mol-ecule of the triangulo-triruthenium complex and one partially occupied disordered chloro-form solvent mol-ecule. The bis-(diphenyl-arsino)methane ligand bridges an Ru-Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine...
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The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(18)H(10)F(5)P)(CO)(9)]·CHCl(3), contains one mol-ecule of the triangulo-triruthenium complex and one mol-ecule of the disordered chloro-form solvent. The bis-(diphenyl-arsino)methane ligand bridges an Ru-Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the arsine and phosphin...
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The asymmetric unit of the title triangulo-triruthenium cluster, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)]·0.5CHCl(3), contains of one mol-ecule of the triangulo-triruthenium complex and half a mol-ecule of the disordered (two positions of equal weight) chloro-form solvent. The bis-(diphenyl-arsino)methane ligand bridges an Ru-Ru bond and the monodentate phosphine ligand bonds to the third ...
متن کاملBis{[μ-bis(diphenylphosphanyl)methane-1:2κ2 P:P′]nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)P(2))(C(19)H(17)PS)(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol-ecule and one half-mol-ecule of the dichloro-methane solvent. The dichloro-methane solvent mol-ecule lies across a crystallographic inversion center leading to the mol-ecule being disordered over two positions of equal occupa...
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